Introduction
The global Cyclohexane Market is poised for significant growth, with its market size expected to reach USD 43.4 billion by 2033, up from USD 26.15 billion in 2023, at a compound annual growth rate (CAGR) of 5.2% during the forecast period from 2023 to 2033. This growth is primarily driven by the increasing demand for cyclohexane in producing nylon, particularly nylon 6 and nylon 66, which are widely used in textiles, automotive, and industrial applications. The rise in industrialization and economic growth in emerging markets further boosts the demand for cyclohexane as it is a critical component in various manufacturing processes.
However, the cyclohexane market faces several challenges. The price volatility of crude oil, from which cyclohexane is derived, significantly impacts production costs and profitability for manufacturers. Additionally, economic downturns can lead to reduced demand from key end-use industries like textiles and automotive, further affecting market growth. Recent developments in the industry include Cepsa’s introduction of a new line of sustainable products and Chevron Phillips Chemical’s expansion of its alpha olefins production, highlighting a trend towards sustainability and increased production capacity to meet growing demand.
Cepsa is a significant player in the cyclohexane market, with production facilities located at its La Rábida refinery in Spain. The company produces approximately 180,000 tons of cyclohexane annually, positioning it as one of the leading producers in Europe. Cepsa integrates its cyclohexane production with its broader petrochemical operations, contributing to the synthesis of intermediates used in the production of nylon, such as cyclohexanol and cyclohexanone. Cyclohexane is a naphthene produced by benzene hydrogenation. Its main use is the synthesis of cyclohexanol/cyclohexanone for the production of the caprolactam and adipic acid, precursors to nylon.
Chevron Phillips chemical company LLC is a prominent producer in the cyclohexane sector, known for its extensive production and marketing capabilities. The company operates some of the largest cyclohexane plants globally, ensuring a robust supply to meet industrial demands. Most cyclohexane goes into the production of intermediates for nylon, which has a variety of common applications such as clothing, tents, and carpets as well as thermoplastics. Cyclohexane is also used as a solvent in chemical and industrial processes and recently has been substituted for benzene in many applications. Chevron Phillips Chemical also offers other solvents through its Specialty Chemicals Division.
Statistics
- A regular hexagon shape contains internal angles of 120 degrees. However, the carbon-carbon bonds belonging to the cyclohexane ring have a tetrahedral symmetry, with the bond angles corresponding to 109.5 degrees.
- It can be noted that at a temperature of 25 degrees Celsius, 99.99% of the molecules belonging to a given cyclohexane solution would correspond to a chair-type conformation.
- To increase the concentration of this conformation, the cyclohexane solution must be heated to 1073K and then cooled to 40K.
- Cyclohexane has a triple point at 279.48 K (6.33 °C) and 5.388 kPa. Its critical point is at 554 K (281 °C) and 4070 kPa. The standard enthalpy change of fusion (Δ_fusH°) is 2.68 kJ/mol, with an entropy change (Δ_fusS°) of 9.57 J/(mol·K).
- Overall prices of Cyclohexane across Europe were recorded to have increased by more than 3% during the time frame 2024.
- Cyclohexane prices in the North American market have demonstrated a bullish trend, despite encountering a substantial drop of approximately 20% in the prices of the feedstock Benzene.
- Towards the conclusion of December 2023, the U.S. automotive industry experienced a notable recovery, with sales witnessing an increase of almost 13%.
- Cyclohexane prices in the APAC region exhibited a notable increase of over 10%, despite the feedstock Benzene experiencing subdued prices with a depreciation exceeding 10%.
- Cyclohexane prices in the European market experienced a predominantly bullish market scenario, demonstrating an increment of approximately 10%, despite the feedstock Benzene facing a bearish trend throughout the entire fourth quarter of 2023.
- The upward movement in prices was primarily propelled by constrained supplies of the product within the Eurozone. The overall contraction of more than 1.5% in industrial chemical production across the Eurozone contributed to a notable scarcity of Cyclohexane, exacerbated by modest demand.
- Cyclohexane has a molar mass of 84.16 g/mol and appears as a colorless liquid with a sweet, gasoline-like odor. It has a density of 0.7781 g/mL in its liquid form. The melting point of cyclohexane is 6.47 °C (43.65 °F; 279.62 K), and its boiling point is 80.74 °C (177.33 °F; 353.89 K).
- Cyclohexane has a vapor pressure of 78 mmHg at 20 °C and a magnetic susceptibility (χ) of -68.13·10⁻⁶ cm³/mol. Its refractive index (n_D) is 1.42662, and it has a viscosity of 1.02 cP at 17 °C.
- Cyclohexane has a monoisotopic mass of 84.09390 g/mol.
- Cyclohexane and benzene with purities of 99.93 mol% and 99.94 mol% are obtained.
- The process aimed to purify an equimolar mixture of 100 kmol/h of cyclohexane-benzene, resulting in concentrations of 99.9 mol% for cyclohexane and 99.6 mol% for benzene.
- The phase diagram of cyclohexane-methanol was thermodynamically modeled in the range of 150 ≤ T/K ≤ 360 and at a pressure of 1 bar based on available experimental data.
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Emerging Trends
Increased Demand for Nylon: The demand for cyclohexane is rising due to its use in producing nylon fibers, essential for the automotive, textile, and packaging industries.
Sustainability Focus: There’s a growing trend towards producing bio-based cyclohexane from renewable feedstocks to address environmental concerns.
Technological Advancements: Innovations in production processes are making cyclohexane manufacturing more efficient and cost-effective.
Regional Growth: The Asia-Pacific and Latin American regions are experiencing significant market growth due to industrialization and expanding automotive and textile sectors.
Product Diversification: Companies are diversifying their cyclohexane offerings to cater to various industrial applications, enhancing their market presence.
Use Cases
Nylon Production: Cyclohexane is primarily used as a raw material in the production of adipic acid and caprolactam, which are essential for manufacturing nylon. This application is significant as nylon is used in numerous products such as carpets, textiles, automotive parts, and industrial fabrics.
Solvent: Due to its non-polar nature, cyclohexane is used as a solvent in chemical reactions and processes. It is effective in dissolving substances like oils, fats, and waxes, making it valuable in the pharmaceutical, cosmetic, and paint industries.
Chemical Synthesis: Cyclohexane is involved in the synthesis of other chemicals. It acts as a precursor in the production of cyclohexanol and cyclohexanone, which are further used to produce other valuable chemicals.
Laboratory Use: In laboratories, cyclohexane is used as a calibration standard in chromatography and as a non-polar solvent for chemical experiments and extractions.
Cleaning Agent: Its ability to dissolve non-polar substances makes cyclohexane useful as a cleaning agent in various industries, including electronics and automotive, where it helps in removing greases and oils.
Key Players Analysis
Cepsa is a significant player in the cyclohexane market, with production facilities located at its La Rábida refinery in Spain. The company produces approximately 180,000 tons of cyclohexane annually, positioning it as one of the leading producers in Europe. Cepsa integrates its cyclohexane production with its broader petrochemical operations, contributing to the synthesis of intermediates used in the production of nylon, such as cyclohexanol and cyclohexanone. Cyclohexane is a naphthene produced by benzene hydrogenation. Its main use is the synthesis of cyclohexanol/cyclohexanone for the production of the caprolactam and adipic acid, precursors to nylon.
https://chemicals.cepsa.com/en/chemical-products/cyclohexane
Chevron Phillips chemical company LLC is a prominent producer in the cyclohexane sector, known for its extensive production and marketing capabilities. The company operates some of the largest cyclohexane plants globally, ensuring a robust supply to meet industrial demands. Most cyclohexane goes into the production of intermediates for nylon, which has a variety of common applications such as clothing, tents, and carpets as well as thermoplastics. Cyclohexane is also used as a solvent in chemical and industrial processes and recently has been substituted for benzene in many applications. Chevron Phillips Chemical also offers other solvents through its Specialty Chemicals Division.
CITGO Petroleum Corporation is actively involved in the cyclohexane sector, focusing on refining and producing high-quality cyclohexane, a key ingredient in manufacturing nylon and other industrial chemicals. Their advanced refining processes ensure consistent product quality, meeting industry standards. CITGO’s strategic position in the U.S. enhances its ability to supply cyclohexane to a variety of end-users, including chemical manufacturers and textile companies.
Reliance Industries Limited is a major player in the cyclohexane market, leveraging its extensive petrochemical infrastructure to produce and supply cyclohexane, a critical raw material in synthetic fibers and resins. Reliance’s robust production capacity and state-of-the-art technology enable them to deliver high-quality cyclohexane to global markets efficiently. Their strategic investments and scale give them a competitive edge in meeting diverse industry needs.
Exxon Mobil Corporation is a major player in the cyclohexane sector, focusing on producing this key chemical for industrial uses. Cyclohexane, derived from crude oil, is vital for manufacturing nylon and other synthetic materials. Exxon Mobil leverages its extensive refining and chemical processing capabilities to supply high-quality cyclohexane. The company’s global reach and advanced technology ensure a steady and reliable supply to meet market demands.
Idemitsu Kosan Co., Ltd. is a significant contributor to the cyclohexane industry, utilizing its refining expertise to produce high-purity cyclohexane. This chemical is essential for creating products such as synthetic fibers and resins. Idemitsu Kosan’s strong focus on innovation and quality ensures its cyclohexane meets rigorous industry standards. Their strategic operations and advanced technologies help maintain a consistent supply chain.
PTT Global Chemical Public Company Limited is a major player in the cyclohexane sector, known for its extensive chemical production capabilities. The company manufactures cyclohexane as part of its diverse chemical portfolio, supporting various industries including automotive and textiles. Their focus on innovation and efficient production processes enhances their market position and meets global demand effectively.
Merck KGaA operates in the cyclohexane sector by providing high-purity cyclohexane for use in scientific and industrial applications. The company’s commitment to quality and research ensures they deliver reliable and consistent products. Their cyclohexane is utilized in laboratories and industrial processes, contributing to advancements in various fields.
Conclusion
Cyclohexane, a saturated hydrocarbon with the chemical formula C₆H₁₂, is a significant industrial chemical primarily used as a precursor in the production of adipic acid and caprolactam, which are essential in the manufacture of nylon. The cyclohexane market is driven by its applications in the production of nylon intermediates, solvents, and specialty chemicals.
Sources
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